The function of Nis 2010's Firewall

Hi! I am trying Nis 2010 and I have a question about Nis's firewall.

 

IfI want to stop manual  a program connecting to the internet.Can i do it by Nis 2010's firewall? and if I can,somebody show me how.

 

I used Comodo firewall pro and it has this function.

 

 example:

If i want to stop firefox connecting to internet by Comodo,I can do : open Comodo/ Fire wall/ View active connection / scroll to the firefox.exe/Click right on it / terminal connection.

 

 

Thanks !